准教授 東野 智洋 研究目録
原著論文
(64) “Graphene Oxide-Fullerene Nanocomposite Laminates for Efficient Hydrogen Purification”
Qi Guo, Behnam Ghalei, Detao Qin, Daizu Mizutani, Ikumi Joko, Habib Al-Aziz, Tomohiro Higashino, Masateru Ito, Hiroshi Imahori, Easan Sivaniah
Chemical Communications, 2023, 59, 10012–10015. (DOI: 10.1039/D3CC02175K)
(63) “Energy Level Tuning of Push-Pull Porphyrin Sensitizer by Trifluoromethyl Group for Dye-Sensitized Solar Cells”
Tomohiro Higashino, Kenichi Sugiura, Keigo Namikawa, Hiroshi Imahori, Journal of Porphyrins and Phthalocyanines, 2023, 27, 145–156. (DOI: 10.1142/S1088424622500778)
(62) “Rational Synthesisof Benzoheterole-fused Porphyrins and π-System Switching by Central Metal Ion”
Tomohiro Higashino, Rikiya Iizumi, Hiroshi Imahori, Chemistry Letters, 2022, 51, 932–935. (DOI: 10.1246/cl.220277)
(61) “Truxenone Triimide: Two-Dimensional Molecular Arrangements of Triangular Molecules for Air Stable n-Type Semiconductors”
Sharvan Kumar, Yun Hee Koo, Tomohiro Higashino, Wakana Matsuda, Samrat Ghosh, Yusuke Tsutsui, Masayuki Suda, Hiroshi Imahori, Katsuaki Suzuki, Hironori Kaji, Shu Seki, Adv. Electron. Mater. 2022, 8, 2101390. (DOI: 10.1002/aelm.202101390)
(60) “Facile Synthesis of an Ambient Stable Pyreno[4,5-b]pyrrole Monoanion and Pyreno[4,5-b:9,10-b’]dipyrrole Dianion: From Serendipity to Design”
Sharvan Kumar, Kohshi Yoshida, Yusuke Hattori, Tomohiro Higashino, Hiroshi Imahori, Shu Seki, Chemical Science, 2022, 13, 1594–1599. (DOI: 10.1039/d1sc06070h)
(59) “Donor-π-Acceptor Type Porphyrin-Fullerene Dyad with Acetylene Bridge for p-Type Dye-Sensitized Solar Cell”
Qi Guo, Tomohiro Higashino, Kosaku Kato, Akira Yamakata, Hiroshi Imahori, Chemistry Letters, 2022, 51, 260–263. (DOI: 10.1246/cl.210717)
(58) “Synthesis of thiophene-fused porphyrin dimers as effective π-extended helical chromophores”
Issei Nishimura, Tomohiro Higashino, Hiroshi Imahori, Chemical Communications, 2021, 57, 9606–9609. (DOI: 10.1039/d1cc04215g)
(Highlighted by Synfacts, 2021, 17, 1211. DOI: 10.1055/s-0040-1720747)
(57)“ Thiophene-Fused Naphthodiphospholes: Modulations of the Structural and Electronic Properties of Polycyclic Aromatics by Precise Fusion of Heteroles”
Keiichi Ishida, Tomohiro Higashino, Yoshimasa Wada, Hironori Kaji, Akinori Saeki, Hiroshi Imahori
ChemPlusChem, 2021, 86, 130–136. (DOI: 10.1002/cplu.202000800)
(56) “Heavy Metal Effects on the Photovoltaic Properties of Metallocorroles in Dye-Sensitized Solar Cells”
Tomohiro Higashino, Yuma Kurumisawa, Abraham Alemayehu, Rune Einrem, Debashis Sahu, Daniel Packwood, Kosaku Kato, Akira Yamakata, Abhik Ghosh, Hiroshi Imahori
ACS Applied Energy Materials, 2020, 3, 12460–12467. (DOI: 10.1021/acsaem.0c02427)
(55) “Exploration on the Combination of Push-Pull Porphyrin Dyes and Copper(I/II) Redox Shuttles toward High-Performance Dye-Sensitized Solar Cells”
Tomohiro Higashino, Hitomi Iiyama, Issei Nishimura, Hiroshi Imahori
Chemistry Letters, 2020, 49, 936–939. (DOI: 10.1246/cl.200317)
(54) “Unique Role of Heterole-fused Structures in Aromaticity and Physicochemical Properties of 7,8-Dehydropurpurins”
Tomohiro Higashino, Issei Nishimura, Hiroshi Imahori
Chemistry –A European Journal, 2020, 26, 12043–12049. (DOI: 10.1002/chem.202001361)
(53) “Simple Processing Additive-Driven 20% Efficiency for Inverted Planar Heterojunction Perovskite Solar Cells”
Sofia Masi, Nicola Sestu, Vitantonio Valenzano, Tomohiro Higashino, Hiroshi Imahori, Michele Saba, Giovanni Bongiovanni, Vincenza Armenise, Antonella Milella, Giuseppe Gigli, Aurora Rizzo, Silvia Colella, Andrea Listorti
ACS Applied Materials & Interfaces, 2020, 12, 18431–18436. (DOI: 10.1021/acsami.9b21632)
(52) “Modulation of Frontier Molecular Orbitals on Dithieno[3,4-b:3’,4’-d]phosphole Derivatives by Donor-π-Acceptor Interaction”
Tomohiro Higashino, Keiichi Ishida, Hiroshi Imahori
Chemistry Letters, 2020, 49, 272–275. (DOI: 10.1246/cl.190879)
(51) “Effect of Ligand Structures of Copeer Redox Shuttles on Photovoltaic Performance of Dye-Sensitized Solar Cells”
Tomohiro Higashino, Hitomi Iiyama, Shimpei Nimura, Yuma Kurumisawa, Hiroshi Imahori
Inorganic Chemistry, 2020, 59, 452–459. (DOI: 10.1021/acs.inorgchem.9b02740)
(50) “Effects of meso-diarylamino group of porphyrins on optical and electrochemical properties”
Tomohiro Higashino, Yamato Fujimori, Issei Nishimura, Hiroshi Imahori
Journal of Porphyrins and Phthalocyanines, 2020, 24, 67–74. (DOI: 10.1142/S1088424619500652)
(49) “Phosphole-fused Dehydropurpurins via Titanium-mediated [2+2+1] Cyclization Strategy”
Tomohiro Higashino, Issei Nishimura, Hiroshi Imahori
Chemistry –A European Journal, 2019, 25, 13816–13823. (DOI: 10.1002/chem.201903269)
(48) “Thiazolocatechol: Electron-withdrawing Catechol Anchoring Group for Dye-Sensitized Solar Cells”
Tomohiro Higashino, Hitomi Iiyama, Yuma Kurumisawa, Hiroshi Imahori
ChemPhysChem, 2019, 20, 2689–2695. (DOI: 10.1002/cphc.201900342)
(47) “Renaissance of Fused Porphyrins: Substituted Methylene-Bridged Thiophene-Fused Strategy for High-Performance Dye-Sensitized Solar Cells”
Yuma Kurumisawa, Tomohiro Higashino, Shimpei Nimura, Yukihiro Tsuji, Hitomi Iiyama, Hiroshi Imahori
Journal of the American Chemical Society, 2019, 141, 9910–9919. (DOI: 10.1021/jacs.9b03302)
京都大学プレスリリース
(46) “Photoconductivity in Metal‐Organic Framework Thin Films”
Xiaojing Liu, Mariana Kozlowska, Timur Okkali, Danny Wagner, Tomohiro Higashino, Gerald Brenner-Weiß, Stefan M. Marschner, Zhihua Fu, Qiang Zhang, Hiroshi Imahori, Stefan Bräse, Wolfgang Wenzel, Christof Wöll, Lars Heinke
Angewandte Chemie International Edition, 2019, 58, 9590–9595. (DOI: 10.1002/anie.201904475)
(45) Pluripotent Features of Doubly Thiophene-fused Benzodiphospholes as Organic Functional Materials”
Tomohiro Higashino, Keiichi Ishida, Tsuneaki Sakurai, Shu Seki, Tatsuki Konishi, Kenji Kamada, Hiroshi Imahori
Chemistry – A European Journal, 2019, 25, 6425–6438. (DOI: 10.1002/chem.201900661)
(44) “Synthesis of Phosphole-bridged Porphyrin Dimers”
Tomohiro Higashino, Issei Nishimura, Hiroshi Imahori
Chemistry Letters, 2019, 48, 257–259. (DOI: 10.1246/cl.180943)
(43) “ABC-ABC-Type meso-meso Directly Linked Porphyrin Dimer”
Tomohiro Higashino, Yuma Kurumisawa, Hitomi Iiyama, Hiroshi Imahori
Chemistry – A European Journal, 2019, 25, 538–547. (DOI: 10.1002/chem.201805405)
(Selected as a HOT Paper) (Selected as Front Cover)
(42) “Cleaner synthesis and systematical characterization of sustainable poly(isosorbide-co-ethylene terephthalate) by environ-benign and highly active catalysts”
Xin-Gui Li, Ge Song, Mei-Rong Huang, Tomoya Ohara, Hiroki Yamada, Tomokazu Umeyama, Tomohiro Higashino, Hiroshi Imahori
Journal of Cleaner Production, 2019, 206, 483–497. (DOI: 10.1016/j.jclepro.2018.09.046)
(41) “Reversible π-system switching of thiophene-fused thiahexaphyrins by solvent and oxidation/reduction”
Tomohiro Higashino, Atsushi Kumagai, Shigeyoshi Sakaki, Hiroshi Imahori
Chemical Science, 2018, 9, 7528–7539. (DOI: 10.1039/c8sc02448k)
(40) “Calix[5]phyrin for Fluoride Ion Sensing with Visible and Near Infrared Optical Responses”
Tomohiro Higashino, Atsushi Kumagai, Hiroshi Imahori
Chemistry – An Asian Journal, 2018, 13, 2019–2022. (DOI: 10.1002/asia.201800856)
(39) “cis-1 Isomers of tethered bismethano [70]fullerene as electron acceptors in organic photovoltaics”
Tomokazu Umeyama, Shogo Takahara, Sho Shibata, Kensho Igarashi, Tomohiro Higashino, Kenji Mishima, Koichi Yamashita, Hiroshi Imahori
RSC Advances, 2018, 8, 18316–18326. (DOI: 10.1039/c8ra02896f)
(38) “Phosphole-Thiophene Hybrid: A Dual Role of Dithieno[3,4-b:3’,4’-d]phosphole as Electron Acceptor and Electron Donor”
Tomohiro Higashino, Keiichi Ishida, Takaharu Satoh, Yoshihiro Matano, Hiroshi Imahori
The Journal of Organic Chemistry, 2018, 83, 3397–3402. (DOI: 10.1021/acs.joc.8b00030)
(37) “Enhanced Donor-π-Acceptor Character of A Porphyrin Dye with Naphthobisthiadiazole for Efficient Near Infrared Light Absorption”
Tomohiro Higashino, Yuma Kurumisawa, Shimpei Nimura, Hitomi Iiyama, Hiroshi Imahori
European Journal of Organic Chemistry, 2018, 2537–2547. (DOI: 10.1002/ejoc.201701736)
(36) “Photovoltaic Properties and Long-Term Durability of Porphyrin-Sensitized Solar Cells with Silicon-Based Anchoring Groups”
Tomohiro Higashino, Shimpei Nimura, Kenichi Sugiura, Yuma Kurumisawa, Yukihiro Tsuji, Hiroshi Imahori
ACS Omega, 2017, 2, 6958–6967. (DOI: 10.1021/acsomega.7b01290)
(35) “A Hydroxamic Acid Anchoring Group for Durable Dye-Sensitized Solar Cells Incorporating a Cobalt Redox Shuttle”
Tomohiro Higashino, Yuma Kurumisawa, Ning Cai, Yamato Fujimori, Yukihiro Tsuji, Shimpei Nimura, Daniel Packwood, Jaehong Park, Hiroshi Imahori
ChemSusChem, 2017, 10, 3347–3351. (DOI: 10.1002/cssc.201701157)
(34) “Synthesis of Partially meso-Free 2,3-Di(arylethynyl)porphyrins”
Tomohiro Higashino, Yuta Ohashi, Hiroshi Imahori
Chemistry Letters, 2017, 46, 976–978. (DOI: 10.1246/cl.170350)
(33) “Enantiomerically Separated α-[70]PCBM for Organic Photovoltaics”
Tomokazu Umeyama, Sho Shibata, Kensho Igarashi, Shogo Takahara, Tomohiro Higashino, Shu Seki, Hiroshi Imahori
Chemistry Letters, 2017, 46, 1001–1003. (DOI: 10.1246/cl.170306)
(32) “Thiophene-fused dithiaoctaphyrins: π-system switching between cross-conjugated and macrocyclic π-networks”
Tomohiro Higashino, Atsushi Kumagai, Hiroshi Imahori
Chemical Communications, 2017, 53, 5091–5094. (DOI: 10.1039/c7cc01273j) (Selected as Inside Front Cover)
(Highlighted by Synfacts, 2017, 13, 820. DOI: 10.1055/s-0036-1590720)
(31) “Hexaphyrin as a Potential Theranostic Dye for Photothermal Therapy and 19F Magnetic Resonance Imaging”
Tomohiro Higashino, Hirotaka Nakatsuji, Ryosuke Fukuda, Haruki Okamoto, Hirohiko Imai, Tetsuya Matsuda, Hidehito Tochio, Masahiro Shirakawa, Nikolai V. Tkachenko, Mitsuru Hashida, Tatsuya Murakami, Hiroshi Imahori
ChemBioChem, 2017, 18, 951–959. (DOI: 10.1002/cbic.201700071) (Selected as Front Cover)
(30) “Unsymmetrically Substituted D–π–A-Type 5,15-Diazaporphyrin Sensitizers: Synthesis and Optical and Photovoltaic Properties”
Satoshi Omomo, Yukihiro Tsuji, Kenichi Sugiura, Tomohiro Higashino, Haruyuki Nakano, Hiroshi Imahori, Yoshihiro Matano
ChemPlusChem, 2017, 82, 695–704. (DOI: 10.1002/cplu.201700051)
(29) “Structural Effects on the Incident Photon-to-Current Conversion Efficiency of Zn Porphyrin Dyes on the Low-Index Planes of TiO2”
Ryo Ide, Yamato Fujimori, Yukihiro Tsuji, Tomohiro Higashino, Hiroshi Imahori, Hideki Ishikawa, Akihito Imanishi, Ken-ichi Fukui, Masashi Nakamura, Nagahiro Hoshi
ACS Omega, 2017, 2, 128–135. (DOI: 10.1021/acsomega.7b00013)
(28) “Regioisomer Effects of [70]Fullerene Mono-adduct Acceptors in Bulk Heterojunction Polymer Solar Cells”
Tomokazu Umeyama, Tetsushi Miyata, Andreas C. Jakowetz, Sho Shibata, Kei Kurotobi, Tomohiro Higashino, Tomoyuki Koganezawa, Masahiko Tsujimoto, Simon Gélinas, Wakana Matsuda, Shu Seki, Richard H. Friend, Hiroshi Imahori
Chemical Science, 2017, 8, 181–188. (DOI: 10.1039/c6sc02950g)
(27) “Remarkable Dependence of Exciplex Decay Rate on Through-Space Separation Distance Between Porphyrin and Chemically Converted Graphene”
Tomokazu Umeyama, Takuma Hanaoka, Jinseok Baek, Tomohiro Higashino, Fawzi Abou-Chahine, Nikolai Tkachenko, Hiroshi Imahori
The Journal of Physical Chemistry C, 2016, 120, 28337–28344. (DOI: 10.1021/acs.jpcc.6b10325)
(26) “Fusing Porphyrins and Phospholes: Synthesis and Analysis of a Phosphorus-Containing Porphyrin”
Tomohiro Higashino, Tomoki Yamada, Tsuneaki Sakurai, Shu Seki, Hiroshi Imahori
Angewandte Chemie International Edition, 2016, 55, 12311–12315. (DOI: 10.1002/anie.201607417) (Selected as a HOT Paper)
(Highlighted in ChemistryViews)
(25) “A New Class of Epitaxial Porphyrin Metal–Organic Framework Thin Films with Extremely High Photocarrier Generation Efficiency: Promising Materials for All-Solid-State Solar Cells”
Jinxuan Liu, Wencai Zhou, Jianxi Liu, Yamato Fujimori, Tomohiro Higashino, Hiroshi Imahori, Xue Jiang, Jijun Zhao, Tsuneaki Sakurai, Yusuke Hattori, Wakana Matsuda, Shu Seki, Suresh Kumar Garlapati, Subho Dasgupta, Engelbert Redel, Licheng Sun, Christof Wöll
Journal of Materials Chemistry A, 2016, 4, 12739–12747. (DOI: 10.1039/c6ta04898f)
(24) “A Push-Pull Porphyrin Dimer with Multiple Electron-Donating Groups for Dye-Sensitized Solar Cells: Excellent Light-Harvesting in Near-Infrared Region”
Tomohiro Higashino, Kenichi Sugiura, Yukihiro Tsuji, Shimpei Nimura, Seigo Ito, Hiroshi Imahori
Chemistry Letters, 2016, 45, 1126–1128. (DOI: 10.1246/cl.160591)
(23) “Effects of Bulky Substituents of Push-Pull Porphyrins on Photovoltaic Properties of Dye-Sensitized Solar Cells”
Tomohiro Higashino, Kyosuke Kawamoto, Kenichi Sugiura, Yamato Fujimori, Yukihiro Tsuji, Kei Kurotobi, Seigo Ito, Hiroshi Imahori
ACS Applied Materials & Interfaces, 2016, 8, 15379–15390. (DOI: 10.1021/acsami.6b03806)
(22) “Combined Experimental and Theoretical Investigations on Optical Activities of Möbius Aromatic and Möbius Antiaromatic Hexaphyrin Phosphorus Complexes”
Tadashi Mori, Takayuki Tanaka, Tomohiro Higashino, Kota Yoshida, Atsuhiro Osuka
The Journal of Physical Chemistry A, 2016, 120, 4241–4248. (DOI: 10.1021/acs.jpca.6b03978)
(21) “Remarkable Dependence of the Final Charge Separation Efficiency on the Donor-Acceptor Interaction in Photoinduced Electron Transfer”
Tomohiro Higashino, Tomoki Yamada, Masanori Yamamoto, Akihiro Furube, Nikolai V. Tkachenko, Taku Miura, Yasuhiro Kobori, Ryota Jono, Koichi Yamashita, Hiroshi Imahori
Angewandte Chemie International Edition, 2016, 55, 629–633. (DOI: 10.1002/anie.201509067)
(20) “Effects of Immersion Solvent on Photovoltaic and Photophysical Properties of Porphyrin-Sensitized Solar Cells”
Hironobu Hayashi, Tomohiro Higashino, Yuriko Kinjo, Yamato Fujimori, Kei Kurotobi, Pavel Chabera, Villy Sundström, Seiji Isoda, Hiroshi Imahori
ACS Applied Materials & Interfaces, 2015, 7, 18689–18696. (DOI: 10.1021/acsami.5b05163)
(19) “Synthesis and Isolation of cis-2 Regiospecific Ethylene-Tethered Indene Dimer–[70]Fullerene Adduct for Polymer Solar Cell Applications”
Ran Tao, Tomokazu Umeyama, Tomohiro Higashino, Tomoyuki Koganezawa, Hiroshi Imahori
ACS Applied Materials & Interfaces, 2015, 7, 16676–16685. (DOI: 10.1021/acsami.5b04351)
(18) “Push-Pull Bacteriochlorin: Panchromatic Sensitizer for Dye-Sensitized Solar Cell”
Tomohiro Higashino, Yukihiro Tsuji, Yamato Fujimori, Kenichi Sugiura, Seigo Ito, Hiroshi Imahori
Chemistry Letters, 2015, 44, 1395–1397. (DOI: 10.1246/cl.150602)
(17) “Hybrid [5]Radialenes with Bispyrroloheteroles: New Electron-Donating Units”
Tomohiro Higashino, Hiroshi Imahori
Chemistry – A European Journal, 2015, 21, 13375–13381. (DOI: 10.1002/chem.201501822)
(16) “Tropolone as a High-Performance Robust Anchoring Group for Dye-Sensitized Solar Cells”
Tomohiro Higashino, Yamato Fujimori, Kenichi Sugiura, Yukihiro Tsuji, Seigo Ito, Hiroshi Imahori
Angewandte Chemie International Edition, 2015, 54, 9052–9056. (DOI: 10.1002/anie.201502951)
(15) “A Single cis-2 Regioisomer of Ethylene-Tethered Indene Dimer–Fullerene Adduct as an Electron-Acceptor in Polymer Solar Cells”
Ran Tao, Tomokazu Umeyama, Tomohiro Higashino, Tomoyuki Koganezawa, Hiroshi Imahori
Chemical Communications, 2015, 51, 8233–8236. (DOI: 10.1039/C5CC01712B)
(14) “A Mobius Aromatic [28]Hexaphyrin Bearing a Diethylamine Group: A Rigid but Smooth Conjugation Circuit”
Tomohiro Higashino, Takanori Soya, Woojae Kim, Dongho Kim, Atsuhiro Osuka
Angewandte Chemie International Edition, 2015, 54, 5456–5459. (DOI: 10.1002/anie.201500099)
(13) “Synthesis of Push-Pull Porphyrin with Two Electron-Donating and Two Electron-Withdrawing Groups and Its Application to Dye-Sensitized Solar Cell”
Tomohiro Higashino, Yamato Fujimori, Kenichi Sugiura, Yukihiro Tsuji, Seigo Ito, Hiroshi Imahori
Journal of Porphyrins and Phthalocyanines, 2015, 19, 140–149. (DOI: 10.1142/S1088424614500989)
(12) “Diprotonated [28]Hexaphyrins(1.1.1.1.1.1): Triangular Antiaromatic Macrocycles”
Shin-ichiro Ishida, Tomohiro Higashino, Shigeki Mori, Hirotaka Mori, Naoki Aratani, Takayuki Tanaka, Jong Min Lim, Dongho Kim, Atsuhiro Osuka
Angewandte Chemie International Edition, 2014, 53, 3427–3431. (DOI: 10.1002/anie.201400301)
(11) “Covalently Linked 5,15-Diazaporphyrin Dimers: Promising Scaffolds for a Highly Conjugated Azaporphyrin π System”
Yoshihiro Matano, Daisuke Fujii, Tarou Shibano, Ko Furukawa, Tomohiro Higashino, Haruyuki Nakano, Hiroshi Imahori
Chemistry – A European Journal, 2014, 20, 3342–3349. (DOI: 10.1002/chem.201304626)
(10) “2,3,17,18-Tetrahalohexaphyrins and the First Phlorin-type Hexaphyrins”
Tomohiro Higashino, Atsuhiro Osuka
Chemistry – An Asian Journal, 2013, 8, 1994–2002. (DOI: 10.1002/asia.201300474)
(Highlighted in ChemistryViews)
(9) “Peripheral Arylations of Subporphyrazines”
Tomohiro Higashino, M. Salomé Rodríguez-Morgade, Atsuhiro Osuka, Tomás Torres
Chemistry – A European Journal, 2013, 19, 10353–10359. (DOI: 10.1002/chem.201301140)
(8) “2,3,17,18-Tetraethylsulfanyl [30]Hexaphyrin(1.1.1.1.1.1) as the First Aromatic Isophlorin-type Free-base”
Tomohiro Higashino, Atsuhiro Osuka
Chemical Science, 2013, 4, 1087–1091. (DOI: 10.1039/c2sc21791k)
(7) “A Möbius Antiaromatic Complex as a Kinetically Controlled Product in Phosphorus Insertion to a [32]Heptaphyrin”
Tomohiro Higashino, Byung Sun Lee, Jong Min Lim, Dongho Kim, Atsuhiro Osuka
Angewandte Chemie International Edition, 2012, 51, 13105–13108. (DOI: 10.1002/anie.201208147)
(6) “Phosphorus Complexes of a Triply-fused [24]Pentaphyrin”
Tomohiro Higashino, Atsuhiro Osuka
Chemical Science, 2012, 3, 103–107. (DOI: 10.1039/c1sc00653c)
(5) “Conformation Dynamics of Non-, Singly-, and Doubly-N-fused [28]Hexaphyrins Revealed by Photophysical Studies”
Jong Min Lim, Mitsunori Inoue, Young Mo Sung, Masaaki Suzuki, Tomohiro Higashino, Atsuhiro Osuka, Dongho Kim
Chemical Communications, 2011, 47, 3960–3962. (DOI: 10.1039/C0CC05822J)
(4) “tert-Butoxide-Mediated Arylation of Benzene with Aryl Halides in the Presence of a Catalytic 1,10-Phenanthroline Derivative”
Eiji Shirakawa, Ken-ichi Itoh, Tomohiro Higashino, Tamio Hayashi
Journal of the American Chemical Society, 2010, 132, 15537–15539. (DOI: 10.1021/ja1080822)
(3) “Singly N-Fused Möbius Aromatic [28]Hexaphyrins(1.1.1.1.1.1)”
Tomohiro Higashino, Mitsunori Inoue, Atsuhiro Osuka
The Journal of Organic Chemistry, 2010, 75, 7958–7961. (DOI: 10.1021/jo1018156)
(2) “Möbius Antiaromatic Bisphosphorus Complexes of [30]Hexaphyrins”
Tomohiro Higashino, Jong Min Lim, Takahiro Miura, Shohei Saito, Jae-Yoon Shin, Dongho Kim, Atsuhiro Osuka
Angewandte Chemie International Edition, 2010, 49, 4950–4954. (DOI: 10.1002/anie.201001765)
(1) “Phosphorus Complexes of the First Expanded Isophlorins”
Takahiro Miura, Tomohiro Higashino, Shohei Saito, Atsuhiro Osuka
Chemistry – A European Journal, 2010, 16, 55–59. (DOI: 10.1002/chem.200902708)
(Highlighted by Synfacts, 2010, 3, 0296. DOI: 10.1055/s-0029-1219267)
総説
(4) “Molecular designs, synthetic strategies, and properties for porphyrins as sensitizers in dye-sensitized solar cells”
Yuzhe Zhang, Tomohiro Higashino, Hiroshi Imahori
J. Mater. Chem. A 2023, in press. (DOI: 10.1039/D2TA09264F)
(3) “Emergence of Copper(I/II) Complexes as Third-Generation Redox Shuttles for Dye-Sensitized Solar Cells”
Tomohiro Higashino, Hiroshi Imahori
ACS Energy Letters, 2022, 7, 1926–1938. (DOI: 10.1021/acsenergylett.2c00716)
(2) “Porphyrins as excellent dyes for dye-sensitized solar cells: recent developments and insights”
Tomohiro Higashino, Hiroshi Imahori
Dalton Transactions, 2015, 44, 448–463. (DOI: 10.1039/c4dt02756f)
(1) “Boron and Phosphorus Complexes of meso-Aryl Expanded Porphyrins”
Tomohiro Higashino, Atsuhiro Osuka
Heterocycles, 2013, 87, 31–54. (DOI: 10.3987/REV-12-757)
著書
(1) “新規π拡張ポルフィリンを用いた色素増感太陽電池”
東野智洋, 今堀 博（分担） 人工光合成—システム構築に向けての最新技術動向と展望— 福住俊一編, シーエムシー出版, 2013, p201–210.
招待講演
(1) “典型元素を用いた新奇な環拡張ポルフィリンの化学”
東野智洋, 第248回分子工学コロキウム, 京都大学, 京都, 2014/06/13
(2) “Möbius Antiaromatic Phosphorus Complexes of meso-Aryl-substituted Expanded Porphyrins”
Tomohiro Higashino, 2015 Reaxys PhD Prize Symposium, Hong Kong, 2015/09/07
(3) “Novel Porphyrinoid with Main Group Elements”
Tomohiro Higashino, Seminar at Karlsruher Institut für Technologie (KIT), Karlsruhe, Germany, 2016/01/21
(4) “Developments of Porphyrinoids with Radialene-type Heteroles”
Tomohiro Higashino, Reaxys Prize Clubシンポジウムin Japan 2018, 日本大学, 千葉, 2018/03/22
(5) “Development of Anchoring Groups for Durable Porphyrin-Sensitized Solar Cells”
Tomohiro Higashino, Hiroshi Imahori, 10th International Conference on Porphyrins & Phthalocyanines (ICPP-10), Munich, Germany, 2018/06/01–06
(6) “Thiophene-fused Expanded Porphyrins with π-System Switching”
Tomohiro Higashino, Hiroshi Imahori, The 235th ECS Meeting, Dallas, TX, USA, 2019/05/26–31
(7) “Thiophene-fused Phosphole Derivatives as Phosphole-Thiophene Hybrid Molecules”
Tomohiro Higashino, Hiroshi Imahori, The 9th East Asia Symposium on Functional Dyes and Advanced Materials, Taipei, Taiwan, 2019/09/17–19
(8) “ポルフィリン色素の精密設計による分子構造と色素増感太陽電池性能の相関解明”
東野智洋, 第1回動的エキシトン若手セミナー, Zoom講演会, 2021年1月27日
(9) “ポルフィリン色素の精密設計による分子構造と色素増感太陽電池性能の相関解明”
東野智洋, 日本化学会第101春季年会（若い世代の特別講演会）,オンライン, 2021年3月21日
(10)“Development of Porphyrin Dyes and Evaluation of Photovoltaic Performances of the Dye-Sensitized Solar Cells”
Tomohiro Higashino, ICPAC Kota Kinabalu 2022，Sabah, Malaysia (Hybrid), 2022/11/22–27
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(2) 日刊工業新聞「京大、太陽電池向け色素開発 エネ変換効率10％超」2019年6月13日朝刊
(3) 日本経済新聞（電子版）「京大、新規ポルフィリン色素の開発に成功－世界最高の太陽光エネルギー変換効率実現へ」2019年6月13日
受賞
2013年4月 日本化学会第93春季年会（2013）学生講演賞
2015年9月 2015 Reaxys PhD Prize Finalist
2016年2月 第32回井上研究奨励賞
2018年4月 日本化学会第98春季年会（2018）優秀講演賞（学術）
2021年3月 日本化学会第101春季年会（2021）第35回若い世代の特別講演会
